Allyltri-n-butyltin, 97%, Thermo Scientific Chemicals

Description

Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

Solubility
Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 24850-33-7
• Molecular Formula: C15H32Sn
• Molecular Weight (g/mol): 331.13
• MDL Number: MFCD00010346
• InChI Key: YLGRTLMDMVAFNI-UHFFFAOYSA-N
• Synonym: allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
• PubChem CID: 90628
• SMILES: CCCC[Sn](CCCC)(CCCC)CC=C

• Density: 1.079
• Boiling Point: 100°C to 102°C (0.5 mmHg)
• Flash Point: 103°C (217°F)
• Refractive Index: 1.486
• Quantity: 25 g
• UN Number: UN2788
• Beilstein: 3588340
• Sensitivity: Air sensitive
• Solubility Information: Immiscible with water.
• IUPAC Name: tributyl(prop-2-en-1-yl)stannane
• Formula Weight: 331.12
• Percent Purity: 97%
• Chemical Name or Material: Allyltri-n-butyltin

Safety and Handling

Hazard Category	H301-H312-H315-H319-H372
Hazard Statement	GHS H Statement H301-H372-H312-H315-H319 Toxic if swallowed. Causes damage to organs through prolonged or repeated exposure. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation.
Precautionary Statement	P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c
DOTInformation	Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOTIN COMPOUNDS, LIQUID, N.O.S.
EINECSNumber	246-494-3
TSCA	No
Recommended Storage	Keep cold; Store under Argon

SDS

RUO – Research Use Only